Explanation: The activity that a forensic examiner should perform first when determining the priority of digital evidence collection at a crime scene is to establish the order of volatility. The order of volatility is a guideline that defines the sequence or the order in which the digital evidence should be collected, preserved, or analyzed, based on the volatility or the fragility of the evidence. The order of volatility helps to ensure that the most volatile or the most easily lost or altered evidence is collected first, and that the least volatile or the most stable or persistent evidence is collected last. The order of volatility also helps to prevent or minimize the contamination, corruption, or destruction of the evidence, and to maintain the integrity, authenticity, or admissibility of the evidence. The order of volatility typically follows this sequence: registers, cache, random access memory (RAM), routing table, kernel statistics, processes, network connections, executable files, temporary file systems, disk, remote logging and monitoring data, physical configuration, network topology, archival media. Gathering physical evidence, assigning responsibilities to personnel on the scene, or establishing a list of files to examine are not the activities that a forensic examiner should perform first when determining the priority of digital evidence collection at a crime scene, as they are not related to the order of volatility. Gathering physical evidence is an activity that involves collecting, documenting, or packaging the physical or tangible evidence, such as devices, media, or peripherals, that may contain or store the digital or intangible evidence, such as data, files, or logs. Assigning responsibilities to personnel on the scene is an activity that involves delegating or distributing the tasks or roles to the forensic team members or other authorized personnel, such as law enforcement, first responders, or witnesses, that are present or involved in the crime scene. Establishing a list of files to examine is an activity that involves identifying or selecting the files or the data that are relevant, significant, or useful for the forensic investigation, such as system files, user files, or hidden files. References: Official (ISC)2 Guide to the CISSP CBK, Fifth Edition, Chapter 19: Security Operations, page 1910.